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Beilstein J. Org. Chem. 2007, 3, No. 37, doi:10.1186/1860-5397-3-37
Graphical Abstract
Figure 1: Piclavines A1-A4.
Scheme 1: Enantiomeric enhancement by iterative AD.
Scheme 2: Asymmetric synthesis of indolidines 209D using an iterative AD.
Scheme 3: Asymmetric synthesis of piclavines A1 and A2 from (2R-[4S])-15.
Scheme 4: Asymmetric synthesis of piclavines A3 and A4 from (2R-[4R])-15.
Scheme 5: Asymmetric synthesis of enantiomers of piclavines (1–4).